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We have used ALMA imaging (resolutions 0.1–0.4 arcsec) of ground and vibrationally excited lines of HCN and HC3N toward the nucleus of NGC 4945 to trace the protostellar phase in super star clusters (proto-SSC). Out of the 14 identified SSCs, we find that eight are in the proto-SSC phase showing vibrational HCN emission with five of them also showing vibrational HC3N emission. We estimate proto-SSC ages of 5–9.7 × 104 yr. The more evolved ones, with only HCN emission, are close to reach the zero-age main sequence (ZAMS; ages ≳105 yr). The excitation of the parental cloud seems to be related to the SSC evolutionary stage, with high (∼65 K) and low (∼25 K) rotational temperatures for the youngest proto and ZAMS SSCs, respectively. Heating by the H ii regions in the SSC ZAMS phase seems to be rather local. The youngest proto-SSCs are located at the edges of the molecular outflow, indicating SSC formation by positive feedback in the shocked regions. The proto-SSCs in NGC 4945 seem to be more evolved than in the starburst galaxy NGC 253. We propose that sequential SSC formation can explain the spatial distribution and different ages of the SSCs in both galaxies.

Methylamine has been the only simple alkylamine detected in the interstellar medium for a long time. With the recent secure and tentative detections of vinylamine and ethylamine, respectively, dimethylamine has become a promising target for searches in space. Its rotational spectrum, however, has been known only up to 45 GHz until now. Here we investigate the rotation-tunnelling spectrum of dimethylamine in selected regions between 76 and 1091 GHz using three different spectrometers in order to facilitate its detection in space. The quantum number range is extended to J = 61 and Ka = 21, yielding an extensive set of accurate spectroscopic parameters. To search for dimethylamine, we refer to the spectral line survey ReMoCA carried out with the Atacama Large Millimeter/submillimeter Array towards the high-mass star-forming region Sagittarius B2(N) and a spectral line survey of the molecular cloud G+0.693–0.027 employing the IRAM 30 m and Yebes 40 m radio telescopes. We report non-detections of dimethylamine towards the hot molecular cores Sgr B2(N1S) and Sgr B2(N2b) as well as G+0.693−0.027 which imply that dimethylamine is at least 14, 4.5, and 39 times less abundant than methylamine towards these sources, respectively. The observational results are compared to computational results from a gas-grain astrochemical model. The modelled methylamine to dimethylamine ratios are compatible with the observational lower limits. However, the model produces too much ethylamine compared with methylamine which could mean that the already fairly low levels of dimethylamine in the models may also be too high.

Using high angular resolution ALMA observations (0.02 arcsec ≈ 0.34 pc), we study the thermal structure and kinematics of the proto-super star cluster 13 in the central region of NGC 253 through their continuum and vibrationally excited HC3N emission from J = 24−23 and J = 26−25 lines arising from vibrational states up to v4 = 1. We have carried 2D-LTE and non-local radiative transfer modelling of the radial profile of the HC3N and continuum emission in concentric rings of 0.1 pc width. From the 2D-LTE analysis, we found a Super Hot Core (SHC) of 1.5 pc with very high vibrational temperatures (>500 K), and a jump in the radial velocity (21 km s−1) in the SE-NW direction. From the non-local models, we derive the HC3N column density, H2 density, and dust temperature (Tdust) profiles. Our results show that the thermal structure of the SHC is dominated by the greenhouse effect due to the high dust opacity in the IR, leading to an overestimation of the LTE Tdust and its derived luminosity. The kinematics and Tdust profile of the SHC suggest that star formation was likely triggered by a cloud–cloud collision. We compare proto-SSC 13 to other deeply embedded star-forming regions, and discuss the origin of the $L_\text{IR}/M_{\text{H}_2}$ excess above ∼100 L⊙ M$_\odot ^{-1}$ observed in (U)LIRGs.

Context.In recent times, large organic molecules of exceptional complexity have been found in diverse regions of the interstellar medium.

Aims.In this context, we aim to provide accurate frequencies of the ground vibrational state of two key aliphatic aldehydes,n-butanal and its branched-chain isomer, i-butanal, to enable their eventual detection in the interstellar medium. We also want to test the level of complexity that interstellar chemistry can reach in regions of star formation.

Methods.We employ a frequency modulation millimeter-wave absorption spectrometer to measure the rotational features ofn- andi-butanal. We analyze the assigned rotational transitions of each rotamer separately using theA-reduced semirigid-rotor Hamiltonian. We use the spectral line survey ReMoCA performed with the Atacama Large Millimeter/submillimeter Array to search forn- andi-butanal toward the star-forming region Sgr B2(N). We also search for both aldehydes toward the molecular cloud G+0.693−0.027 with IRAM 30 m and Yebes 40 m observations. The observational results are compared with computational results from a recent gas-grain astrochemical model.

Results.Several thousand rotational transitions belonging to the lowest-energy conformers of two distinct linear and branched isomers have been assigned in the laboratory spectra up to 325 GHz. A precise set of the relevant rotational spectroscopic constants has been determined for each structure as a first step toward identifying both molecules in the interstellar medium. We report non-detections ofn-and i-butanal toward both sources, Sgr B2(N1S) and G+0.693-0.027. We find thatn- andi-butanal are at least 2-6 and 6-18 times less abundant than acetaldehyde toward Sgr B2(N1S), respectively, and thatn-butanal is at least 63 times less abundant than acetaldehyde toward G+0.693−0.027. While propanal is not detected toward Sgr B2(N1S) either, with an abundance at least 5–11 lower than that of acetaldehyde, propanal is found to be 7 times less abundant than acetaldehyde in G+0.693−0.027. Comparison with astrochemical models indicates good agreement between observed and simulated abundances (where available). Grain-surface chemistry appears sufficient to reproduce aldehyde ratios in G+0.693−0.027; gas-phase production may play a more active role in Sgr B2(N1S). Model estimates for the larger aldehydes indicate that the observed upper limits may be close to the underlying values.

Conclusions.Our astronomical results indicate that the family of interstellar aldehydes in the Galactic center region is characterized by a drop of one order of magnitude in abundance at each incrementation in the level of molecular complexity.

Using 0.2 arcsec (∼3 pc) ALMA images of vibrationally excited HC3N emission (HC3N*) we reveal the presence of eight unresolved Super Hot Cores (SHCs) in the inner 160 pc of NGC 253. Our LTE and non-LTE modelling of the HC3N* emission indicate that SHCs have dust temperatures of 200–375 K, relatively high H2 densities of (1−6) × 106 cm−3 and high IR luminosities of (0.1–1) × 108 L⊙. As expected from their short-lived phase (∼104 yr), all SHCs are associated with young super star clusters (SSCs). We use the ratio of luminosities from the SHCs (protostar phase) and from the free–free emission (ZAMS star phase), to establish the evolutionary stage of the SSCs. The youngest SSCs, with the larges ratios, have ages of a few 104 yr (proto-SSCs) and the more evolved SSCs are likely between 105 and 106 yr (ZAMS-SSCs). The different evolutionary stages of the SSCs are also supported by the radiative feedback from the UV radiation as traced by the HNCO/CS ratio, with this ratio being systematically higher in the young proto-SSCs than in the older ZAMS-SSCs. We also estimate the SFR and the SFE of the SSCs. The trend found in the estimated SFE ($\sim 40{{\ \rm per\ cent}}$ for proto-SSCs and $\gt 85{{\ \rm per\ cent}}$ for ZAMS-SSCs) and in the gas mass reservoir available for star formation, one order of magnitude higher for proto-SSCs, suggests that star formation is still going on in proto-SSCs. We also find that the most evolved SSCs are located, in projection, closer to the centre of the galaxy than the younger proto-SSCs, indicating an inside-out SSC formation scenario.